РУС ENG
Министерство науки и высшего образования Российской Федерации
Российская Академия Наук

Laboratory of Carbocyclic Compounds (N10)

Chief:
Main directions of research

Head: Yuri N. Bubnov, Full Member of RAS (e-mail: borioc.ac.ru, tel. +7(499)137-7319)

The laboratory was established in 1936 by Prof. M. A. Il'inskii, Hon. Memb. Acad. Sc., as Laboratory of Intermediates and Dyes (1936-1939). It was headed by Full Member of the Academy A.E. Porai-Koshits (1939-1949) and I.V. Obreimov (1949-1954). Prof. B.M. Mikhailov, Associated Member of Acad. Sc., headed it in 1954-1984 and exactly at that time Laboratory received its present name and specialization.

Research areas

Chemistry of organoboron compounds, their reactivity, and applications in the multi-purpose organic synthesis.

 Design of novel boron structures: unsaturated, cyclic and cage compounds.

 Development of "boron" methods of the organic synthesis.

 Synthesis of natural products and their analogs via organoboranes.

 Sigmatropic rearrangements of organoboranes, including borotropy.

Main results

Allylborated organic compounds with multiple bonds, allylboron-acetylene condensation, reductive mono- and trans-a,a'-diallylation of nitrogen heterocycles by allyl boranes, and a permanent allyl rearrangement in allylboranes were discovered.

 Using organoboranes, total syntheses of muscarin, ernanducin, (+)- and (-) CABOB, ipsenol, ipsidienol, dihydropinidine, epihydropinidine, indolisidins 1676B and 209D, pseudoheliotridane, remantadin, and derivatives of 1-boron- and 1-azaadamantane were performed. 

 
Institute News
Researchers of the Zelinsky Institute have proposed a reagent for the photocatalytic activation of the carbon-halogen bond Researchers of the Zelinsky Institute have proposed a reagent for the photocatalytic activation of the carbon-halogen bond
The breaking of the carbon-halogen bond is quite widely used to generate organic carbon-centered radicals. Among the alkyl halides, chlorine derivatives…
ZIOC researchers published a review on the use of quaternary ammonium compounds in the fight against resistant bacterial colonies. ZIOC researchers published a review on the use of quaternary ammonium compounds in the fight against resistant bacterial colonies.
The vast majority of pathogens are found in the environment in the form of surface-bound microbial communities called biofilms. The unique protective properties…
Scientists of the Zelinsky Institute studied the reaction of diphenyl disulfide with Lappert's germylene Scientists of the Zelinsky Institute studied the reaction of diphenyl disulfide with Lappert's germylene
The use of transition metals catalysis provoked the rapid development of organic chemistry in the second half of the 20th century and continues to play…
The research on the photochemistry of diarylethenes is continued in the Zelinsky Institute The research on the photochemistry of diarylethenes is continued in the Zelinsky Institute
In recent decades, the photochemistry of diarylethenes and their derivatives has been actively developing. One of the areas of development of this area…
ZIOC scientists synthesized new water-soluble substances with high antiproliferative activity ZIOC scientists synthesized new water-soluble substances with high antiproliferative activity
Nitrogen- and sulfur-containing heterocyclic structures have a wide range of biological activity and are part of a large number of drugs. Among these compounds,…
A framework for analyzing real-time electron microscopy data was developed in the ZIOC A framework for analyzing real-time electron microscopy data was developed in the ZIOC
Electron microscopy is one of the most widely used methods for studying the structure of materials, biological objects, and complex chemical systems of…

Laboratory of Carbocyclic Compounds (N10) Head: Yuri N. Bubnov, Full Member of RAS (e-mail: borioc.ac.ru, tel. +7(499)137-7319) The laboratory was established in 1936 by Prof. M. A. Il'inskii, Hon. Memb. Acad. Sc., as Laboratory of Intermediates and Dyes (1936-1939). It was headed by Full Member of the Academy A.E. Porai-Koshits (1939-1949)… ST LUCE https://zioc.ru/ 5 100 .00 RUB http://schema.org/InStock